Chandrasekhar V., Pointillart F. (ed.) Organometallic Magnets

Springer Nature Switzerland AG, 2019. — 418 p. — (Topics in Organometallic Chemistry 64). — ISBN: 978-3-030-26008-8.This volume highlights the recent advances and state of art in the experimental and theoretical studies of organometallic magnets. A plethora of organic ligands such as Mannich-base derivatives, redox-active chromophores, cyanides, Schiff base among others are used to coordinate to 3d transition metals, 4f lanthanides and 5f actinides to design the molecular magnets. Deep analysis of the coordination sphere symmetry, electronic distribution, luminescence are investigated to perform magneto-structural correlation leading to a better understanding of the magnetic properties. Furthermore, the rationalization of the magnetic behavior can be reached using ab initio calculations. The multiple applications that these molecular magnets offer could revolutionize the high-density data storage, spintronics and quantum computing technologies. This volume provides a discussion of these topics from leading international experts and will be a useful reference for researchers working in this field.Hybrid Organic–Inorganic Cyanide-Bridged Networks
Cobalt(II) Complexes as Single-Ion Magnets
Cobalt(II)/(III)–Lanthanide(III) Complexes as Molecular Magnets
Mannich Base Ligands as Versatile Platforms for SMMs
Tetrathiafulvalene-Based Magnets of Lanthanides
Geometry and Magnetism of Lanthanide Compounds
Single-Ion Anisotropy: An Insight to Complicated Magnetic Molecules
Lanthanide Organometallics as Single-Molecule Magnets
Role of Ab Initio Calculations in the Design and Development of Lanthanide Based Single Molecule Magnets
Complete Active Space Wavefunction-Based Analysis of Magnetization and Electronic Structure
Magnetism of Actinide Coordination Compounds
Correction to: Cobalt(II) Complexes as Single-Ion Magnets
Correction to: Cobalt(II)/(III)–Lanthanide(III) Complexes as Molecular Magnets