Larson Gerald L., Fry James L. Ionic and Organometallic-Catalyzed Organosilane Reductions

Hoboken, New Jersey, Published by John Wiley & Sons, Inc., 2010 by Organic Reactions. 756 p.
ISBN: 978-0-470-54787-8MECHANISM
Role of Trivalent Silicon Species
Role of Hypervalent Silicon Species
Role of O/N-Silylated Cationic Intermediates
Role of Metal Catalysts
SCOPE AND LIMITATIONS
Reduction of Substituted Alkanes
Alcohols to Alkanes
Alkyl Halides and Triflates to Alkanes
Reduction of Unsaturated Hydrocarbons
Alkenes to Alkanes
Alkynes to Alkanes
Cyclopropanes to Alkanes
Aromatic Substrates
Miscellaneous Unsaturated Substrates
Reduction of Ethers
Reduction of Allyl Acetates
Reduction of Carboxylic Acids
Reduction of Acid Halides and Acid Anhydrides
Reduction of Esters and Lactones
Reduction of Aldehydes
Reduction to AlcoholsORGANOSILICON HYDRIDE REDUCTIONS
Reductive Amidation of Aldehydes
Reductive Esterification
Reductive Etherification
Reduction to Alkanes
Reduction to Methylene Halides
Reductive Amination
Reductive Thiolation
Reduction of Ketones
Reduction to Alcohols
Reductive Amidation
Reductive Esterification
Reductive Etherification
Reductive Silylation
Reduction to Halocarbons
Reduction to Alkanes
Reductive Amination
Reductive Thiolation
Miscellaneous Ketone Reductions
Reduction of Amides
Reduction of α,β-Unsaturated Aldehydes
Reduction of α,β-Unsaturated Ketones
Reduction of α,β-Unsaturated Esters
Reduction of α,β-Unsaturated Amides
Reduction of α,β-Unsaturated Nitriles
Reduction of Acetals, Ketals, Hemiacetals, Hemiketals, and Orthoesters
Reduction of Aminals and Hemiaminals
Reduction of Enamines
Reduction of Imines
Reduction of Oximes
Reduction of Nitroalkanes
Reduction of Miscellaneous Nitrogen-Containing Compounds
Reduction of Miscellaneous Sulfur-Containing Compounds
Reduction of Small-Ring Heterocycles
Asymmetric Reduction of Ketones
Asymmetric Reduction of α,β-Unsaturated Ketones
Asymmetric Reduction of α,β-Unsaturated Esters and Lactones
Asymmetric Reduction of α,β-Unsaturated Lactams
Asymmetric Reduction of Imines
COMPARISON WITH OTHER METHODS
Asymmetric Hydrogenation of Olefins
Asymmetric Hydrogenation of Ketones
Asymmetric Hydrogenation of Enol Acetates
Asymmetric Hydrogenation of α,β-Unsaturated Acids
Asymmetric Hydrogenation of Acetamidoacrylates
Asymmetric Hydrogenation of Enamides
Asymmetric Hydrogenation of Imines
EXPERIMENTAL CONDITIONS
EXPERIMENTAL PROCEDURESTABULAR SURVEY