John Wiley & Sons Ltd, West Sussex, UK, 2014. – 589 p. – ISBN: 1119952891.
Metal–Organic Frameworks (MOFs) are crystalline compoundsconsisting of rigid organic molecules held together and organizedby metal ions or clusters. Special interests in these materialsarise from the fact that many are highly porous and can be used forstorage of small molecules, for example H2 or CO2 . Consequently, the materials are ideal candidatesfor a wide range of applications including gas storage, separationtechnologies and catalysis. Potential applications includethe storage of hydrogen for fuel–cell cars, and the removal andstorage of carbon dioxide in sustainable technical processes. MOFsoffer the inorganic chemist and materials scientist a wide range ofnew synthetic possibilities and open the doors to new and excitingbasic research. Metal–Organic Frameworks Materials provides a solid basisfor the understanding of MOFs and insights into new inorganicmaterials structures and properties. The volume also reflectsprogress that has been made in recent years, presenting a widerange of new applications including state–of–the art developmentsin the promising technology for alternative fuels. Thecomprehensive volume investigates structures, symmetry,supramolecular chemistry, surface engineering, recognition,properties, and reactions.
Design and SynthesisPorous Coordination Polymer Nanoparticles and Macrostructures.
Nanoscale Metal-Organic Frameworks.
Mesoporous Metal-Organic Frameworks.
Porphyrinic Metal-Organic Frameworks.
Fluorinated Metal-Organic Frameworks (FMOFs): Concept, Construction, and Properties.
Synthesis and Structures of Aluminum-Based Metal-Organic Frameworks.
Polyrotaxane Metal-Organic Frameworks.
Photoreactive Metal-Organic Frameworks.
Edible Metal-Organic Frameworks.
Mechanochemical Approaches to Metal-Organic Frameworks.
Post-ModificationPostsynthetic Modification of Metal-Organic Frameworks.
Properties and ApplicationsFunctional Magnetic Materials Based on Metal Formate Frameworks.
Metal-Organic Frameworks from Single-Molecule Magnets.
Open Metal Sites in Metal-Organic-Frameworks.
Gas Storage in Metal-Organic Frameworks.
Metal-Organic Frameworks for Removal of Harmful Gases.
Adsorption of Hydrocarbons and Alcohols in Metal-Organic Framework Materials.
Metal Uptake in Metal-Organic Frameworks.
Photoreactive Properties Hosted in Metal-Organic Frameworks.
Semiconducting Metal-Organic Frameworks.
Patterning Techniques for Metal-Organic Frameworks.
Metal-Organic Frameworks in Mixed-Matrix Membranes.
Electrochemical Properties of Metal-Organic Frameworks.
Applications of Metal-Organic Frameworks to Analytical Chemistry.
Recent Solid-State NMR Studies of Quadrupolar Nuclei in Metal-Organic Frameworks.
NETSSingle-Crystal to Single-Crystal Transformations in Metal-Organic Frameworks.
Interpenetration and Entanglement in Coordination Polymers.