Pan Stanford Publishing, 2011. - 525 p. - Tunneling reactions in chemistry are characterized by the low-temperature limit when the classical contribution is negligible. Many practical applications benefit from the lack of heat and have a deep physical basis. Interesting advantages of chemical synthesis at low temperatures have also been demonstrated. This book covers fundamental and practical aspects of the processes and experimental and theoretical methods used in the field. The chapters are written by leading scientists who have very strong experience in the selected topics, and many practical recommendations can be found in this book.
Photoexcitation of Free Radicals and Molecular Ions Trapped in Rare-Gas Solids
Metal Atom Reactions to Form Novel Small Molecules
Conformational Changes in Cryogenic Matrices
Photodynamics at Low Temperatures, in Time Domain
Matrix Isolation of H and D Atoms: Physics and Chemistry from 1.5 to 0.1 K
Matrix Isolation Spectroscopy in Solid Parahydrogen: A Primer
Matrix Isolation Spectroscopy in Helium Droplets
Cryogenic Solutions as a Tool to Characterize Red- and Blue-Shifting C−H…X Hydrogen Bonding
Low-Temperature Infrared Spectroscopy of Surface Species
Photolysis and Radiolysis of Water Ice
Cool Interstellar Physics and Chemistry
High-Resolution Single-Molecule Spectroscopy in Condensed Matter
Noble-Gas Chemistry
Modeling Structures and Spectra of Trapped Species in Low-Temperature Matrices
Spectroscopy of Biological Molecules at Very Low Temperatures: Theoretical Studies